Anno2013
AutoriPibiri I, Palumbo Piccionello A, Pace A, Barone G, Buscemi S
AbstractThe photoreactivity of allyl benzoates, containing an electron-rich double bond, has been explored by irradiation at 305 nm in different solvents. Solvent addition products arising from an insertion of the alpha H-C bonds of THF, dioxane, and i-PrOH to the allylic double bond was realized. The observed reactivity depended on reaction conditions and substitution pattern of the substrate. A DFT study on this unusual reaction was performed allowing the formulation of two mechanistic pathways.
RivistaTetrahedron
ISSN0040-4020
Impact factor
Volume69
Pagina inizio6065
Pagina fine6069
Autori IBFSilvestre BUSCEMI, Antonio PICCIONELLO PALUMBO
Linee di Ricerca IBFMD.P01.002.001
Sedi IBFIBF.PA